Synthesis and characterization of new metal complexes of thione and phosphines Ligands
DOI:
https://doi.org/10.25130/tjps.v22i9.875الكلمات المفتاحية:
Transition metal, Oxadiazole, Phosphine, Thioneالملخص
The complexes containing mixed of ligands [5-(3-chlorophenyl) -1,3,4-oxadiazole-2-thione(CPoxSH)] and diphosphines Ph2P(CH2)nPPh2 (diphos)(n=1-4), are prepared by the reaction of [Hg(CPoxS)2] or [M(H2O)2(CPoxS)2] (M = Co, Ni ) with one mole proportion of the diphosphine Ph2P(CH2)nPPh2 gave tetrahedral complexes of the type [Hg(CPoxS)2(diphos)]. While gave an octahedral complexes with cobalt(II) and nickel(II) ions of the type [M(H2O)(CPoxS)2(diphos)] when (M = Co and Ni ) receptivity.
The prepared complexes were characterized by molar conductivity, elemental analysis, IR, 1H, 13C-{1H} and 31P-{1H} n.m.r.
التنزيلات
منشور
كيفية الاقتباس
إصدار
القسم
الرخصة
الحقوق الفكرية (c) 2023 Tikrit Journal of Pure Science
هذا العمل مرخص بموجب Creative Commons Attribution 4.0 International License.
Tikrit Journal of Pure Science is licensed under the Creative Commons Attribution 4.0 International License, which allows users to copy, create extracts, abstracts, and new works from the article, alter and revise the article, and make commercial use of the article (including reuse and/or resale of the article by commercial entities), provided the user gives appropriate credit (with a link to the formal publication through the relevant DOI), provides a link to the license, indicates if changes were made, and the licensor is not represented as endorsing the use made of the work. The authors hold the copyright for their published work on the Tikrit J. Pure Sci. website, while Tikrit J. Pure Sci. is responsible for appreciate citation of their work, which is released under CC-BY-4.0, enabling the unrestricted use, distribution, and reproduction of an article in any medium, provided that the original work is properly cited.
