Synthesis and Spectroscopic study of Pd(II)- Salicylaldoxime complexes with amine ligands
DOI:
https://doi.org/10.25130/tjps.v26i3.140Keywords:
Salicylaldoxime; Palladium; oxime; 2,2'-bipyridyl; 1,10-phenanthroline.Abstract
New Pd(II) complexes of Salicylaldoxime (HSaly) with amine ligands {amine = Bipy, Phen and en} were synthesized and characterized by using CHN analysis, FT-IR spectra, molar conductivity and 1H NMR spectra. The HSaly ligand was coordinated with the Pd(II) ion as bidentate chelating ligand in complex [Pd(Saly)2], through oxygen atom of hydroxylate group and nitrogen atom of oxime group. However, it was bonded as monodentate ligand in complexes [Pd(Saly)2(amine)] (2-4) via the oxygen atom of hydroxylate group. The amines were coordinated as bidentate chelate via N atom to give a square planner around the Palladium (II).
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