Preparation and characterization of some Transition Metal Complexes the first and second with (1-methyl-3-Piperidine Xanthate potassium) and ethylenediamine
DOI:
https://doi.org/10.25130/tjps.v22i12.933الملخص
This research includes the preparation of a number of new tetra xanthate complexes diheterometal of some transition metal of Co(II), Ni(II), Cu(II), and non transition metal of Zn(II) and Cd(II) by reacting the metal salts with the ligand (1-methyl-3-piperidine xanthate) to form complexes of formula of [M{Ag(1-Me-3-pipXant)2}2] (A), [MM`(1-Me-3-pipXant)4] (B), where M=Co(II), Ni(II), Cu(II), M`= Cd(II), Zn(II) and These complexes were reacted with ethylendiamine to form an adduct of the general formula [M(en)3][M(1-Me-3-pipXant)2}2] (I.A), [M(en)3][M`(1-Me-3-pipXant)4] (I.B). All the prepared complexes have been characterized and studied by element analysis, molar conductance, magnetic susceptibility, infrared and electronic spectral.
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