Synthesis and Spectroscopic study of Pd(II)- Salicylaldoxime complexes with amine ligands

  • Emad N. Al_Sabawi
  • Ahmed S. Al-Janabi2
  • Hayfa Muhammed Jerjes1

Abstract

New Pd(II) complexes  of Salicylaldoxime (HSaly) with amine ligands {amine = Bipy, Phen and en} were synthesized and characterized by using CHN analysis, FT-IR spectra, molar conductivity and 1H NMR spectra. The HSaly ligand was coordinated with the Pd(II) ion as bidentate chelating ligand in complex [Pd(Saly)2], through oxygen atom of hydroxylate group and nitrogen atom of oxime group, whereas, bonded as monodentate ligand in complexes [Pd(Saly)2(amine)] (2-4), via the oxygen atom of hydroxylate group, and the amines were coordinated as bidentate chelate via N atom to give a square planner around the Palladium (II).


 


http://dx.doi.org/10.25130/tjps.26.2021.045

Published
Jul 10, 2021
How to Cite
AL_SABAWI, Emad N.; AL-JANABI2, Ahmed S.; JERJES1, Hayfa Muhammed. Synthesis and Spectroscopic study of Pd(II)- Salicylaldoxime complexes with amine ligands. Tikrit Journal of Pure Science, [S.l.], v. 26, n. 3, p. 26-34, july 2021. ISSN 2415-1726. Available at: <https://tjps.tu.edu.iq/index.php/j/article/view/1146>. Date accessed: 22 sep. 2021. doi: http://dx.doi.org/10.25130/j.v26i3.1146.
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Articles